A Honeycomb-Like Crystalline Self-Assembled Hexadeca-Substituted Phthalocyanine

Atsay A., NAR I., Hamuryudan E., KOCAK M., Guel A.

CHEMISTRYSELECT, cilt.2, sa.28, ss.9233-9235, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2 Sayı: 28
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1002/slct.201702078
  • Dergi Adı: CHEMISTRYSELECT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.9233-9235
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Hexadeca-substituted metal-free and zinc(II) phthalocyanines carrying alkoxy substituents on non-peripheral(alpha) and 4-(dimethylamino)phenyl-ethynyl groups on peripheral(beta) positions have been synthesized and characterized by spectroscopic techniques. The complexes show Q band beyond 800 nm. Zinc phthalocyanine forms an intermolecular zinc-nitrogen coordination and self assembles to a chain-like coordination polymer and the coordination chains stack together in an elongated honeycomb-like fashion in the crystal lattice.