MACROAZOINITIATORS FOR THE PREPARATION OF POLYMERS WITH CYCLOBORAZANE UNITS

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FRITZ P., YAGCI Y.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, pp.75-79, 1995 (SCI-Expanded)

• Publication Type: Article / Article
• Publication Date: 1995
• Doi Number: 10.1080/10601329508020316
• Journal Name: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.75-79
• Istanbul Technical University Affiliated: Yes

Abstract

Macroazoinitiators containing cyclodiborazane moieties and various amounts of-N=N- units in the main chain were prepared by polyaddition between thexyl borane and adipoyldinitrile (AD) with the addition of 2,2'azobis(isobutyronitrile) (AIBN) at room temperature. These polymers were employed in the polymerization of styrene (St) to afford polystyrene with cyclodiborazane groups.