MACROAZOINITIATORS FOR THE PREPARATION OF POLYMERS WITH CYCLOBORAZANE UNITS


FRITZ P., YAGCI Y.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, pp.75-79, 1995 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 1995
  • Doi Number: 10.1080/10601329508020316
  • Title of Journal : JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Page Numbers: pp.75-79

Abstract

Macroazoinitiators containing cyclodiborazane moieties and various amounts of-N=N- units in the main chain were prepared by polyaddition between thexyl borane and adipoyldinitrile (AD) with the addition of 2,2'azobis(isobutyronitrile) (AIBN) at room temperature. These polymers were employed in the polymerization of styrene (St) to afford polystyrene with cyclodiborazane groups.