Fabrication of chitosan-aminopropylsilane graphene oxide nanocomposite hydrogel embedded PES membrane for improved filtration performance and lead separation

Amiri S., Asghari A., Vatanpour Sargheın V., Rajabi M.

JOURNAL OF ENVIRONMENTAL MANAGEMENT, cilt.294, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 294
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1016/j.jenvman.2021.112918
  • Dergi Adı: JOURNAL OF ENVIRONMENTAL MANAGEMENT
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, International Bibliography of Social Sciences, PASCAL, Aerospace Database, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, CAB Abstracts, Communication Abstracts, EMBASE, Environment Index, Geobase, Greenfile, Index Islamicus, MEDLINE, Metadex, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Civil Engineering Abstracts
  • Anahtar Kelimeler: Nanofiltration membrane, Nanocomposite hydrogel, Heavy metal removal, Dye wastewater, Antifouling, WASTE-WATER TREATMENT, NANOFILTRATION MEMBRANES, COMPOSITE MEMBRANES, DYE REMOVAL, HIGH-FLUX, POLYETHERSULFONE, PB(II), ADSORPTION, STABILITY, REDUCTION
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

In the present study chitosan-aminopropylsilane graphene oxide (CS-APSGO) nanocomposite hydrogel was synthesized and utilized as a hydrophilic additive in different dosages (0.5, 1, 2 and 5 wt%) in fabrication of porous polyethersulfone (PES) membranes via the phase inversion induced process by immersion precipitation method for heavy metal ion and dye removal. The modified membranes were characterized using ATR-FTIR, AFM, SEM, water contact angle, overall porosity and mean pore radius evaluations and zeta potential measurement. The addition of CS-APSGO nanocomposite hydrogel to PES doping solutions enhanced membranes hydrophilicity and consequently pure water flux permeability. Filtration performance of the CS-APSGO embedded membranes showed promising antifouling properties during BSA filtration test (FRR> 90%) and 1 wt% membranes showed the highest pure water flux of 123.8 L/m2 h with BSA rejection more than 98% and removal capability more than 82% for lead (II) ion, 90.5% and 98.5% for C.I. Reactive Blue 50 and C.I. Reactive Green 19, respectively. Therefore, the CS-APSGO nanocomposite hydrogel blending in order to modification of PES-based membranes have a noticeable potential in improving filtration performance of blended membranes.