Effect of the promoter presence in catalysts on the compositions of Fischer-Tropsch synthesis products

Uykun Mangaloğlu, Deniz; Baranak, Murat; Atac, Ozlem; Atakül, Hüsnü

doi:10.1016/j.jiec.2018.05.044

Effect of the promoter presence in catalysts on the compositions of Fischer-Tropsch synthesis products

Atıf İçin Kopyala

Uykun Mangaloğlu D., Baranak M., Atac O., Atakül H.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, cilt.66, ss.298-310, 2018 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 66
Basım Tarihi: 2018
Doi Numarası: 10.1016/j.jiec.2018.05.044
Dergi Adı: JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.298-310
İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The effects of alkali promoters namely potassium, copper, and manganese, on the performance of the bifunctional iron-low acidity ZSM-5 catalysts in the Fischer-Tropsch (FT) synthesis were studied. ZSM-5 with very high silica alumina ratio (SAR) of 280 was used to take advantage of its shape selectivity and suppressing the effect of alkali migration on zeolite cation exchange sites. One bi-functional iron base catalyst (FeZ), three single promoted (KFeZ, CuFeZ, MnFeZ) and four multiple promoted (CuKFeZ, CuMnFeZ, KMnFeZ, CuKMnFeZ) catalysts were synthesized by the incipient to wetness impregnation method. They were characterized by XRD, BET, TPR, TEM and TPD analyses methods and tested for their FT synthesis activities.