The effect of macrocycles on the reaction rate - Part V. The effect of [18]crown-6 on the aromatic nucleophilic substitution reactions in dioxane-water solutions.


Tuncer H., Erk C.

9th International Symposium on Molecular Recognition and Inclusion (ISMRI 9), Lyon, France, 7 - 12 September 1996, pp.531-534 identifier

  • Publication Type: Conference Paper / Full Text
  • City: Lyon
  • Country: France
  • Page Numbers: pp.531-534

Abstract

The effect of 1,4,7,10,13,16-hexaoxacyclooctadecane, [18]crown-6 on the rate of reaction of 2,4-dinitrochlorobenzene and NaN3 was investigated in water / dioxane (50/50) mixtures. The second order bimolecular reaction rates were estimated with a chloride selective electrode located in the solution The.