Synthesis of Terpolymers by Click Reactions


Altintas O., Tunca Ü.

CHEMISTRY-AN ASIAN JOURNAL, vol.6, no.10, pp.2584-2591, 2011 (Journal Indexed in SCI) identifier identifier identifier

  • Publication Type: Article / Review
  • Volume: 6 Issue: 10
  • Publication Date: 2011
  • Doi Number: 10.1002/asia.201100138
  • Title of Journal : CHEMISTRY-AN ASIAN JOURNAL
  • Page Numbers: pp.2584-2591
  • Keywords: catalysis, copper, cycloaddition, radicals, terpolymers, RING-OPENING POLYMERIZATION, MIKTOARM STAR TERPOLYMERS, ONE-POT SYNTHESIS, AZIDE-ALKYNE CYCLOADDITION, H-SHAPED TERPOLYMERS, DIELS-ALDER REACTION, RADICAL POLYMERIZATION, BLOCK-COPOLYMERS, THERMO-RESPONSIBILITY, TRIBLOCK TERPOLYMERS

Abstract

Well-defined polymeric structures were easily generated through living polymerization systems, in particular, living radical polymerizations. The polymeric precursors with orthogonal functionalities were subsequently clicked together with single or double (combinatorial) click reactions, such as the copper-catalyzed azide-cycloadditions (CuAAC) and Diels-Alder reactions, to create a wide variety of linear and nonlinear terpolymers.