Removal of Lead(II) from Aqueous Solutions using Pre-boiled and Formaldehyde-Treated Onion Skins as a New Adsorbent


Saka C., Sahin Ö., Demir H., Kahyaoglu M.

SEPARATION SCIENCE AND TECHNOLOGY, vol.46, no.3, pp.507-517, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 46 Issue: 3
  • Publication Date: 2011
  • Doi Number: 10.1080/01496395.2010.517595
  • Journal Name: SEPARATION SCIENCE AND TECHNOLOGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.507-517
  • Keywords: adsorbent, adsorption, isotherm, kinetic, onion skin, Pb2+, INDUSTRY WASTE-WATER, ACTIVATED CARBON, ION-EXCHANGE, ADSORPTION, PEEL, HYDROXIDE, CHROMIUM, PB(II), PB2+
  • Istanbul Technical University Affiliated: No

Abstract

The adsorption characteristics of Pb2+ on pre-boiled treated onion skins (PTOS) and formaldehyde-treated onion skins (FTOS) were evaluated. The effects of Pb2+ initial concentration, agitation rate, solution pH, and temperature on Pb2+ adsorption were investigated in batch systems. Pb2+ adsorption was found to increase with increase in initial concentration. The point of zero net charge (PZC) was 6.53. The optimum pH for the maximum removal of Pb2+ was 6.0. The adsorption equilibrium data was best represented by the Langmuir isotherm model for FTOS and the Freundlich isotherm model for PTOS. The maximum amounts of Pb2+ adsorbed (qm), as evaluated by the Langmuir isotherm, was 200 mgg-1 for FTOS. The efficiencies of PTOS and FTOS for Pb2+ removal were 84,8.0% and 93.5% at 0.15g/200mL-1 adsorbent dose, respectively. (C0=50mg L-1). Study concluded that onion skins, a waste material, have good potential as an adsorbent to remove toxic metals like Pb2+ from water. Boehm titration analysis was conducted to determine the surface groups. It was found that the adsorption kinetics of Pb2+ obeyed pseudo-first-order kinetic model as based on q (%) values. FTIR and SEM images before and after adsorption was recorded to explore changes in adsorbent-surface morphology. Activation energy (Ea) was obtained as 25.596kJ/mol.