A novel (E,E)-dioxime and its mono-, di- and trinuclear complexes bearing tetradentate octyl sulfanyl phenylamino substituents. Synthesis, characterization and electrochemical properties of its transition metal complexes

Kandaz M., CORUHLU S., Yilmaz I. , OZKAYA A.

TRANSITION METAL CHEMISTRY, cilt.27, ss.877-883, 2002 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 27 Konu: 8
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1023/a:1021359012365
  • Sayfa Sayıları: ss.877-883


A new vic-dioxime, 13,14-bis-(hydroxyimino)-9,12,15,18-diazadithiaoctacosane, has been synthesized from 2-octylsulfanylaminobenzene and (E, E')-dichloroglyoxime. Mononuclear transition metal complexes of Ni-II, Cu-II, Co-II and Fe-II have been prepared and were found to have a metal-ligand ratio of 1:2. The synthesis of di- and trinuclear complexes was achieved with (UO2)-O-IV and Cu-II depending on the stoichiometry of the reactants. The complexes were characterized by elemental analysis, H-1-n.m.r., u.v.-vis, i.r., f.a.b.-m.s. and by cyclic voltammetry.