Photocatalytic and Antimicrobial Properties of Electrospun TiO2-SiO2-Al2O3-ZrO2-CaO-CeO2 Ceramic Membranes

Yerli Soylu N., Soylu A., Dikmetaş D. N., Karbancıoğlu Güler H. F., Kucukbayrak S., Erol Taygun M.

ACS Omega, vol.8, no.12, pp.10836-10850, 2023 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 8 Issue: 12
  • Publication Date: 2023
  • Doi Number: 10.1021/acsomega.2c06986
  • Journal Name: ACS Omega
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Directory of Open Access Journals
  • Page Numbers: pp.10836-10850
  • Istanbul Technical University Affiliated: Yes


In this study, TiO2-based ceramic nanofiber membranes in the system of TiO2-SiO2-Al2O3-ZrO2-CaO-CeO2 were synthesized by combining sol-gel and electrospinning processes. In order to investigate the thermal treatment temperature effect, the obtained nanofiber membranes were calcined at different temperatures ranging from 550 to 850 °C. Different characterization methods such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), and high-resolution transmission electron microscopy (HR-TEM) were conducted on the obtained membranes to investigate the structural and morphological properties of the nanofibers. The Brunauer-Emmett-Teller surface area of the nanofiber membranes was very high (46.6-149.2 m2/g) and decreased with increasing calcination temperature as expected. Photocatalytic activity investigations were determined using methylene blue (MB) as a model dye under UV and sunlight irradiation. High degradation performances were achieved with the calcination temperatures of 650 and 750 °C because of the high specific surface area and the anatase structure of the nanofiber membranes. Moreover, the ceramic membranes showed antibacterial activity against Escherichia coli as a Gram-negative bacterium and Staphylococcus aureus as a Gram-positive bacterium. The superior properties of the novel TiO2-based multi-oxide nanofiber membranes proved as a promising candidate for various industries, especially the removal of textile dyes from wastewater.