Soluble and conductive polypyrrole copolymers containing silicone tegomers


Kizilcan N., Ustamehmetoglu B., OZ N., SARAC A., AKAR A.

JOURNAL OF APPLIED POLYMER SCIENCE, cilt.89, sa.11, ss.2896-2901, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 89 Sayı: 11
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1002/app.12140
  • Dergi Adı: JOURNAL OF APPLIED POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2896-2901
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Soluble and processable conductive copolymers of silicone tegomers and pyrrole were developed. This was easily accomplished by the oxidative polymerization of pyrrole monomer by Ce(IV) salt in the presence of silicone tegomers with hydroxyl chain ends. The resulting copolymers were soluble in dimethylformamide. The products were characterized by Fourier transform infrared, H-1-NMR, and four-point probe conductivity, and their surface properties were investigated with contact-angle measurements. (C) 2003 Wiley Periodicals, Inc.