Photomediated controlled radical polymerization

Pan X., TAŞDELEN M. A., Laun J., Junkers T., Yagci Y., Matyjaszewski K.

PROGRESS IN POLYMER SCIENCE, cilt.62, ss.73-125, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Derleme
  • Cilt numarası: 62
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.progpolymsci.2016.06.005
  • Dergi Adı: PROGRESS IN POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.73-125
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed. (C) 2016 Elsevier Ltd. All rights reserved.