Effects of ultrasound on zeolite A synthesis

Andac O., Tatlier M., Sirkecioglu A., Ece I., ERDEM-SENATALAR A.

MICROPOROUS AND MESOPOROUS MATERIALS, cilt.79, ss.225-233, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.micromeso.2004.11.007
  • Dergi Adı: MICROPOROUS AND MESOPOROUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.225-233
  • Anahtar Kelimeler: ultrasound, zeolite A, crystallization, adsorption, thermogravimetric analysis, CRYSTALLIZATION, SONOLUMINESCENCE, BATCH, POWER, SIZE
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Synthesis of zeolite A from a clear-to-the-eye sodium alummosilicate solution was carried out in the presence of ultrasound at different temperatures and times and the results were compared to those obtained by performing conventional static syntheses under similar conditions. It was possible to obtain highly crystalline zeolite A in the presence of ultrasound, which influenced the types and stability areas of the phases that formed during metastable phase transformations. Nucleation and crystallization rates, as well as the yield of zeolite A increased as a result of the application of ultrasound. Thermogravimetric analyses and water adsorption experiments revealed that the development of micropore adsorption capacity, which started very early in the X-ray amorphous samples obtained from this so-called "clear" solution, was also speeded up with the application of ultrasound. (c) 2004 Elsevier Inc. All rights reserved.