Synthesis of block copolymers by mechanistic transformation from photoinitiated cationic polymerization to a RAFT process


Puglisi A., Murtezi E., Yilmaz G., Yagci Y.

POLYMER CHEMISTRY, cilt.8, sa.47, ss.7307-7310, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 8 Sayı: 47
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1039/c7py01707c
  • Dergi Adı: POLYMER CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7307-7310
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

A novel synthetic strategy for the synthesis of block copolymers based on mechanistic transformation from photoinitiated cationic polymerization to radical addition fragmentation transfer polymerization is presented. The process yielded polytetrahydrofuran-bpoly(methyl methacrylate), which was fully characterized by spectroscopic, chromatographic and thermal analyses.