Preparation of fly ash Ca(OH)(2) sorbents by pressure hydration for SO2 removal


ENERGY SOURCES, vol.20, no.10, pp.945-953, 1998 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 10
  • Publication Date: 1998
  • Doi Number: 10.1080/00908319808970109
  • Title of Journal : ENERGY SOURCES
  • Page Numbers: pp.945-953


Reactive sorbents for SO2 removal from humidified flue gas were prepared from fly ash-Ca(OH)(2) mixtures using the pressure hydration technique. The fly ash samples were taken from three different coal-fired power plants in Turkey. The fly ash/Ca(OH)(2) weight ratio, hydration time, and temperature were varied during the sorbent preparation step. Effects of these variations on the physical properties of activated sorbents were investigated. A statistical design technique was applied by use of a two-level factorial design matrix to interpret experimental results. It was found that increasing the temperature and fly ash/Ca(OH)(2) weight ratio caused a decrease in the total surface area of sorbents. However, surface area values of sorbents were not generally affected by the hydration time variation. Finally, fly ash-Ca(OH)(2) sorbents prepared at the optimum hydration conditions were sulphated at 338 K with a synthetic gaseous mixture containing 5000 ppm SO2 and 55% relative humidity.