Highly active and stable CeO2 supported nickel-complex catalyst in hydrogen generation


Kilinc D., Sahin Ö.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, vol.46, no.1, pp.499-507, 2021 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 46 Issue: 1
  • Publication Date: 2021
  • Doi Number: 10.1016/j.ijhydene.2020.09.201
  • Journal Name: INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Artic & Antarctic Regions, Chemical Abstracts Core, Communication Abstracts, Environment Index, INSPEC
  • Page Numbers: pp.499-507
  • Keywords: CeO2, Ni-complex, NaBH4, Hydrogen generation, SCHIFF-BASE COMPLEX, SODIUM-BOROHYDRIDE, CRYSTAL-STRUCTURE, HYDROLYSIS, METHANOL, STORAGE, CARBON, MECHANISM, INSIGHTS, ETHANOL
  • Istanbul Technical University Affiliated: No

Abstract

Cerium oxide supported 5-Amino-2,4-dichlorophenol-3,5-ditertbutylsalisylaldimine-Nickel complex for the first time was used to produce H-2 from hydrolysis of sodium borohydride. Cerium oxide supported Nickel complex catalyzed hydrolysis systemwas studied depend on temperature, concentration of sodium hydroxide, amount of Cerium oxide supported Ni complex catalyst, concentration of Ni complex and concentration of sodium borohydride. Cerium oxide supported Ni(II) complex display highly effective catalytic activity in sodium borohydride hydrolysis reaction. The obtained Ceriumoxide supportedNi(II) complex catalyst was characterized by using Fourier Transform Infrared Spectroscopy, Scanning Electron Microscope, Transmission ElectronMicroscope, Brunauer-Emmett-Teller Surface Area Analysis, X-Ray Diffraction Analysis techniques. The catalyst stability was tested, even the fifth recycle the catalytic activity was maintained at 100%. Additionally the proposed Cerium oxide supported-Ni (II) complex catalyzed sodium borohydride hydrolysis mechanism was determined carefully. The experimental results showed that Ceriumoxide supported Ni (II) complex catalyst accelerate sodium borohydride hydrolysis with 43,392 and 19,630 mL H-2 g(cat)(-1) min(-1) hydrogenproductionratesat 50 degrees C and 30 degrees C respectively and20,587 kJ mol(-1) activationenergy. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.