Hydrogen storage performance of the multi-principal-component CoFeMnTiVZr alloy in electrochemical and gas-solid reactions


Sarac B., Zadorozhnyy V., Berdonosova E. A. , Ivanov Y. P. , Klyamkin S., Gumrukcu S., ...More

RSC ADVANCES, vol.10, no.41, pp.24613-24623, 2020 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 10 Issue: 41
  • Publication Date: 2020
  • Doi Number: 10.1039/d0ra04089d
  • Journal Name: RSC ADVANCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Biotechnology Research Abstracts, Chemical Abstracts Core, Compendex, Metadex, Directory of Open Access Journals
  • Page Numbers: pp.24613-24623
  • Istanbul Technical University Affiliated: Yes

Abstract

The single-phase multi-principal-component CoFeMnTiVZr alloy was obtained by rapid solidification and examined by a combination of electrochemical methods and gas-solid reactions. X-ray diffraction and high-resolution transmission electron microscopy analyses reveal a hexagonal Laves-phase structure (type C14). Cyclic voltammetry and electrochemical impedance spectroscopy investigations in the hydrogen absorption/desorption region give insight into the absorption/desorption kinetics and the change in the desorption charge in terms of the applied potential. The thickness of the hydrogen absorption layer obtained by the electrochemical reaction is estimated by high-resolution transmission electron microscopy. The electrochemical hydrogen storage capacity for a given applied voltage is calculated from a series of chronoamperometry and cyclic voltammetry measurements. The selected alloy exhibits good stability for reversible hydrogen absorption and demonstrates a maximum hydrogen capacity of similar to 1.9 wt% at room temperature. The amount of hydrogen absorbed in the gas-solid reaction reaches 1.7 wt% at 298 K and 5 MPa, evidencing a good correlation with the electrochemical results.