Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl] (methyl)aminol} ethoxy-substituted metallophthalocyanines


Zengin H. , YENILMEZ H. Y. , BURAT A. K. , BAYIR Z. A.

TURKISH JOURNAL OF CHEMISTRY, cilt.38, ss.1094-1101, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 38 Konu: 6
  • Basım Tarihi: 2014
  • Doi Numarası: 10.3906/kim-1405-26
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.1094-1101

Özet

The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2{[2-(dimethylamino)ethyl](methyl)aminof ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, H-1 NMR, FT-IR, and UV-Vis spectral data.