Synthesis and characterization of novel 2-{[2-(dimethylamino)ethyl] (methyl)aminol} ethoxy-substituted metallophthalocyanines


Zengin H., YENILMEZ H. Y. , BURAT A. K. , BAYIR Z. A.

TURKISH JOURNAL OF CHEMISTRY, vol.38, no.6, pp.1094-1101, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 38 Issue: 6
  • Publication Date: 2014
  • Doi Number: 10.3906/kim-1405-26
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.1094-1101
  • Istanbul Technical University Affiliated: Yes

Abstract

The synthesis of novel, symmetrical, tetrasubstituted metallophthalocyanines (cobalt, zinc, and copper) bearing four 2{[2-(dimethylamino)ethyl](methyl)aminof ethoxy units was reported. The dinitrile derivative was converted into the water-soluble quaternized product by its reaction with methyl iodide. The quaternized zinc phthalocyanine was obtained from the reaction of the water-soluble dinitrile derivative with zinc acetate. The structures of the newly synthesized molecules were proposed according to elemental analysis, H-1 NMR, FT-IR, and UV-Vis spectral data.