Oxidative copolymerization of pyrrole and N-methyl pyrrole


Ustamehmetoglu B. , Kelleboz E., Sarac A.

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION, cilt.8, ss.255-268, 2003 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 8 Konu: 4
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1080/10236660390198448
  • Dergi Adı: INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION
  • Sayfa Sayıları: ss.255-268

Özet

Pyrrole and N-methyl pyrrole were copolymerized by ceric ammonium nitrate (CAN) in aqueous solution. The resulting products were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, and four-point probe conductivity measurements. The specific electrical conductivity of the copolymers can be increased depending on the mole ratio of pyrrole/N-methylpyrrole. The conductivities of copolymers are in the range of 10(-4)-10(-2) S cm(-1). Kinetic parameters were obtained by gravimetric determination of the copolymer and found to be dependent on [pyrrole](0.87) [N-methyl pyrrole](0.06) [CAN](0.11) [H2SO4](1.28) from gravimetric determination.