Zn(II) and Pd(II) complexes of thiosemicarbazone-S-alkyl esters derived from 2/3-formylpyridine


Kizilcikli I., Ulkuseven B., Dasdemir Y., Akkurt B.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, vol.34, no.4, pp.653-665, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 34 Issue: 4
  • Publication Date: 2004
  • Doi Number: 10.1081/sim-120035948
  • Title of Journal : SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
  • Page Numbers: pp.653-665

Abstract

Representative S-methyl/ethyl-4-H/phenylthiosemicarbazones and their Zn(II) and Pd(II) complexes were synthesized. Characterization of the 1:1 complexes, [Zn(L)Cl-2], [Pd(L)Cl-2], and [Pd(L)Cl]Cl, was accomplished by means of elemental analyses, IR and H-1 NMR spectra. The multidentate S-alkyl thiosemicarbazones coordinate as mono-, bi-, or tridentate ligands depending on the types of the alkyl moiety and metal ion.