Photoinduced Controlled Radical Polymerization

TAŞDELEN M. A., UYGUN M., Yagci Y.

MACROMOLECULAR RAPID COMMUNICATIONS, cilt.32, sa.1, ss.58-62, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 32 Sayı: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1002/marc.201000351
  • Dergi Adı: MACROMOLECULAR RAPID COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.58-62
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Well-controlled radical polymerization of methyl methacrylate can be achieved by in situ photochemical generation of copper (I) complex from air-stable copper (II) species without using any reducing agent at room temperature. The living character of this polymerization was confirmed by both the linear tendency of molecular weight evolution with conversion and a chain extension experiment.