Preparation of poly(glycidyl methacrylate) grafted sulfonamide based polystyrene resin with tertiary amine for the removal of dye from water


Senkal B. F. , BILDIK F. , Yavuz E. , SARAC A.

REACTIVE & FUNCTIONAL POLYMERS, cilt.67, ss.1471-1477, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

Özet

Poly(glycidyl methacrylate) was grafted onto crosslinked poly (styrene) beads through the 2-chloroethyl sulphonamide (CSA) groups present in the resin using ATRP polymerization method. A beaded polymer with a poly (glycidyl methacrylate) surface shell was prepared in three steps, starting from poly (styrene-DVB) (10% crosslinking) based beads with a particle size of 420-590 mu m, according to the synthetic protocol; chlorosulfonation, sulfamidation with 2-chloroethylamine hydrochloride and grafting reaction of poly (glycidyl methacrylate).