Preparation of poly(glycidyl methacrylate) grafted sulfonamide based polystyrene resin with tertiary amine for the removal of dye from water


Senkal B. F., BILDIK F., Yavuz E., SARAC A.

REACTIVE & FUNCTIONAL POLYMERS, vol.67, no.12, pp.1471-1477, 2007 (SCI-Expanded) identifier identifier

Abstract

Poly(glycidyl methacrylate) was grafted onto crosslinked poly (styrene) beads through the 2-chloroethyl sulphonamide (CSA) groups present in the resin using ATRP polymerization method. A beaded polymer with a poly (glycidyl methacrylate) surface shell was prepared in three steps, starting from poly (styrene-DVB) (10% crosslinking) based beads with a particle size of 420-590 mu m, according to the synthetic protocol; chlorosulfonation, sulfamidation with 2-chloroethylamine hydrochloride and grafting reaction of poly (glycidyl methacrylate).