Esterification of oleic acid with glycerol in the presence of sulfated iron oxide catalyst

Guner F. S., Sirkecioglu A., YILMAZ S., ERCIYES A. T., ERDEM-SENATALAR A.

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, cilt.73, sa.3, ss.347-351, 1996 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 73 Sayı: 3
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1007/bf02523429
  • Dergi Adı: JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.347-351
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Esterification of oleic acid with glycerol was investigated in view of the reaction kinetics, using ''superacidic'' sulfated iron oxide catalysts. A series of different sulfate contents were prepared and characterized by a multitude of techniques prior to their use as catalysts. The sulfated iron oxide re action was carried out with equivalent amounts of reactants in the temperature range of 180-240 degrees C. Effects of the sulfate con tent and the catalyst amount on reaction kinetics at different temperatures were evaluated.