Starch coated titanium dioxide nanoparticles as a challenging sorbent to separate and preconcentrate some heavy metals using graphite furnace atomic absorption spectrometry

Baysal A., Kuznek C., Özcan M.

INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, vol.98, no.1, pp.45-55, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 98 Issue: 1
  • Publication Date: 2018
  • Doi Number: 10.1080/03067319.2018.1427741
  • Journal Name: INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.45-55
  • Keywords: Graphite furnace atomic absorption spectrometry, lead, cadmium, copper, cobalt, nickel, nanoparticle, solid phase extraction, SOLID-PHASE EXTRACTION, SAMPLES, WATER, TIO2, IONS, ZN, PB, CD, REMOVAL, CADMIUM
  • Istanbul Technical University Affiliated: Yes

Abstract

In this study, a challenging nanosorbent was described for preconcentration/separation method based on the sorption of cadmium, cobalt, copper, nickel, lead on starch coated titanium dioxide nanoparticles and its analysis by graphite furnace atomic absorption spectrometry. Optimum conditions were investigated for quantitative sorption. By using the proposed technique, the analyte elements were determined in spiked tap-water samples in the range of 95% confidence level. Limit of detection (3) was 0.05, 0.28, 1.90, 3.10 and 0.11 mu g/L (3 sigma, N=10) for cadmium, cobalt, copper, nickel and lead, respectively. The optimised technique is fast, easy handled, simple and environmental friendly.