Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts

ONEN, A; ARSU, N; Yagci, Yusuf

doi:10.1002/(sici)1522-9505(19990201)264:1<56::aid-apmc56>3.0.co;2-5

Photoinitiated polymerization of ethyl cyanoacrylate by phosphonium salts

Atıf İçin Kopyala

ONEN A., ARSU N., Yagci Y.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.264, ss.56-59, 1999 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 264
Basım Tarihi: 1999
Doi Numarası: 10.1002/(sici)1522-9505(19990201)264:1<56::aid-apmc56>3.0.co;2-5
Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.56-59
İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The photoinitiated polymerization of ethyl cyanoacrylate (ECA) by benzyl triphenylphosphonium hexafluoroantimonate (BP+) and (anthracen-9-ylmethyl)triphenylphosphonium hexafluoroantimonate (MAP(+)) was studied. Zwitterionic and free radical mechanisms which involved homolytic and heterolytic decomposition of the phosphonium salts are discussed. The anthracene-sensitized photopolymerization of ECA was also demonstrated.