New aminoethylsulfanyl-substituted tribenzoporphyrazines


Korkmaz N., Hamuryudan E.

MONATSHEFTE FUR CHEMIE, cilt.135, sa.5, ss.513-518, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 135 Sayı: 5
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1007/s00706-003-0146-6
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.513-518
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Unsymmetrical metal-free and metalo-porphyrazines (M = Mg, Zn, Co) made up of three phthalonitrile units and a single maleonitrile moiety on the periphery were prepared by cyclization of bis(2-dimethylaminoethylthio)maleonitrile and phthalonitrile. The magnesium derivative (Mgpz) was converted into the quaternized product by reaction with methyl iodide. The new compounds were characterized by elemental analysis, IR, NMR, mass, and electronic spectra.