New aminoethylsulfanyl-substituted tribenzoporphyrazines

Korkmaz N., Hamuryudan E.

MONATSHEFTE FUR CHEMIE, vol.135, no.5, pp.513-518, 2004 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 135 Issue: 5
  • Publication Date: 2004
  • Doi Number: 10.1007/s00706-003-0146-6
  • Journal Name: MONATSHEFTE FUR CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.513-518
  • Istanbul Technical University Affiliated: Yes

Abstract

Unsymmetrical metal-free and metalo-porphyrazines (M = Mg, Zn, Co) made up of three phthalonitrile units and a single maleonitrile moiety on the periphery were prepared by cyclization of bis(2-dimethylaminoethylthio)maleonitrile and phthalonitrile. The magnesium derivative (Mgpz) was converted into the quaternized product by reaction with methyl iodide. The new compounds were characterized by elemental analysis, IR, NMR, mass, and electronic spectra.