New aminoethylsulfanyl-substituted tribenzoporphyrazines

Korkmaz N., Hamuryudan E.

MONATSHEFTE FUR CHEMIE, vol.135, no.5, pp.513-518, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 135 Issue: 5
  • Publication Date: 2004
  • Doi Number: 10.1007/s00706-003-0146-6
  • Title of Journal : MONATSHEFTE FUR CHEMIE
  • Page Numbers: pp.513-518


Unsymmetrical metal-free and metalo-porphyrazines (M = Mg, Zn, Co) made up of three phthalonitrile units and a single maleonitrile moiety on the periphery were prepared by cyclization of bis(2-dimethylaminoethylthio)maleonitrile and phthalonitrile. The magnesium derivative (Mgpz) was converted into the quaternized product by reaction with methyl iodide. The new compounds were characterized by elemental analysis, IR, NMR, mass, and electronic spectra.