Poly(amide thioether)s by addition of ethanedithiol to diallylamides


Bicak N., Karaoglan S.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, vol.258, pp.33-37, 1998 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 258
  • Publication Date: 1998
  • Journal Name: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.33-37
  • Istanbul Technical University Affiliated: No

Abstract

The preparation of poly(amide thioether)s by addition of ethanedithiol to diallylamides in the presence or absence of peroxide catalysts is reported for the first time. Diallylamide monomers N,N'-diallyloxalamide, N,N'-diallylmalonamide and N,N'-diallylterephthalamide have been prepared by aminolysis of the corresponding esters with allylamine. The structures of the resulting polymers have been elucidated by elemental microanalysis and H-1 NMR and IR spectroscopy. The polymers obtained both as Markovnikov and anti-Markovnikov types of addition are highly crystalline compounds.