Poly(amide thioether)s by addition of ethanedithiol to diallylamides


Bicak N., Karaoglan S.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.258, ss.33-37, 1998 (SCI İndekslerine Giren Dergi) identifier

  • Cilt numarası: 258
  • Basım Tarihi: 1998
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Sayfa Sayıları: ss.33-37

Özet

The preparation of poly(amide thioether)s by addition of ethanedithiol to diallylamides in the presence or absence of peroxide catalysts is reported for the first time. Diallylamide monomers N,N'-diallyloxalamide, N,N'-diallylmalonamide and N,N'-diallylterephthalamide have been prepared by aminolysis of the corresponding esters with allylamine. The structures of the resulting polymers have been elucidated by elemental microanalysis and H-1 NMR and IR spectroscopy. The polymers obtained both as Markovnikov and anti-Markovnikov types of addition are highly crystalline compounds.