SYNTHESIS AND CHARACTERIZATION OF PHTHALOCYANINES CONTAINING 4 14-MEMBERED TETRAAZA MACROCYCLES


KOCAK M. , GUREK A., GUL A. , BEKAROGLU O.

CHEMISCHE BERICHTE, cilt.127, sa.2, ss.355-358, 1994 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 127 Konu: 2
  • Basım Tarihi: 1994
  • Doi Numarası: 10.1002/cber.19941270212
  • Dergi Adı: CHEMISCHE BERICHTE
  • Sayfa Sayıları: ss.355-358

Özet

Metal phthalocyanines (M = Cu, Ni, Co, SnCl2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear complex which is extremely soluble in polar solvents. The mass spectrum of the [hexadecakis(N-p-tosyl)-tetrakis-macrocycle-phthalocyaninato]copper(II) 3 is described