SYNTHESIS AND CHARACTERIZATION OF PHTHALOCYANINES CONTAINING 4 14-MEMBERED TETRAAZA MACROCYCLES


KOCAK M. , GUREK A., GUL A. , BEKAROGLU O.

CHEMISCHE BERICHTE, vol.127, no.2, pp.355-358, 1994 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 127 Issue: 2
  • Publication Date: 1994
  • Doi Number: 10.1002/cber.19941270212
  • Title of Journal : CHEMISCHE BERICHTE
  • Page Numbers: pp.355-358

Abstract

Metal phthalocyanines (M = Cu, Ni, Co, SnCl2) 3-6 containing four 14-membered tetraaza macrocycles have been prepared. Detosylation of the aza functions has provided donor sites for binding four Ni2+ ions giving a pentanuclear complex which is extremely soluble in polar solvents. The mass spectrum of the [hexadecakis(N-p-tosyl)-tetrakis-macrocycle-phthalocyaninato]copper(II) 3 is described