Cationic polymerization using allyl sulfonium salt .3. Allyl sulfonium salt ascorbate redox couple

ONEN A., DENIZLIGIL S., Yagci Y.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, cilt.245, ss.149-154, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 245
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1002/apmc.1997.052450113
  • Dergi Adı: ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.149-154
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The cationic polymerization of cyclohexene oxide was initiated by reduction of allyl sulfonium salt in the presence of ascorbyl-6 hexadecanoate and copper(II) benzoate. A redox reaction in which the copper compound serving as an electron carrier for the initiation step was proposed.