Cationic polymerization using allyl sulfonium salt .3. Allyl sulfonium salt ascorbate redox couple


ONEN A., DENIZLIGIL S., Yagci Y.

ANGEWANDTE MAKROMOLEKULARE CHEMIE, vol.245, pp.149-154, 1997 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 245
  • Publication Date: 1997
  • Doi Number: 10.1002/apmc.1997.052450113
  • Title of Journal : ANGEWANDTE MAKROMOLEKULARE CHEMIE
  • Page Numbers: pp.149-154

Abstract

The cationic polymerization of cyclohexene oxide was initiated by reduction of allyl sulfonium salt in the presence of ascorbyl-6 hexadecanoate and copper(II) benzoate. A redox reaction in which the copper compound serving as an electron carrier for the initiation step was proposed.