Metallophthalocyanines with rod-shaped substituents

Kalkan A., AYTEKIN A., Bayir Z.

TRANSITION METAL CHEMISTRY, cilt.31, sa.6, ss.720-723, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 31 Sayı: 6
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1007/s11243-006-0053-x
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.720-723
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

4-(4'-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4'-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et3N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4'-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH3COO)(2), CoCl2 and CuCl2). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by H-1-NMR, C-13-NMR, FT-IR, UV-Vis and mass spectroscopies.