Metallophthalocyanines with rod-shaped substituents

Kalkan A., AYTEKIN A., Bayir Z.

TRANSITION METAL CHEMISTRY, vol.31, no.6, pp.720-723, 2006 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 31 Issue: 6
  • Publication Date: 2006
  • Doi Number: 10.1007/s11243-006-0053-x
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.720-723
  • Istanbul Technical University Affiliated: No

Abstract

4-(4'-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4'-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et3N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4'-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH3COO)(2), CoCl2 and CuCl2). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by H-1-NMR, C-13-NMR, FT-IR, UV-Vis and mass spectroscopies.