Rapid Hyperbranched Polythioether Synthesis Through Thiol-Michael Addition Reaction

Daglar O., Gungor B., Guric G., Günay U. S., Hızal G., Tunca Ü., ...Daha Fazla

JOURNAL OF POLYMER SCIENCE, cilt.58, sa.6, ss.824-830, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 58 Sayı: 6
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1002/pol.20190279
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.824-830
  • Anahtar Kelimeler: hyperbranched polymer, hyperbranched, organocatalyst, polythioether, polysulfides, step-growth polymerization, thiol-Michael, AB(2) MONOMERS, TRANSFER POLYMERIZATION, POLYMERS, CLICK, CHEMISTRY
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

In this study, two types of hyperbranched (HB) polythioether could readily be achieved in a short time at ambient temperature through a thiol-Michael addition reaction. Dimethyl acetylenedicarboxylate (DMADC) or methyl propiolate (A(2)) and trimethylolpropane tris(3-mercaptopropionate) (B-3) monomers were reacted using an organobase 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as a catalyst in chloroform at room temperature to provide subsequent HB polythioethers. The effect of TBD concentration on the polymerization was studied for the DMDAC case monitoring the molecular weight evolution against time. HB polythioethers were characterized using spectroscopic (nuclear magnetic resonance) and chromatographic (gel permeation chromatography with refractive index and light-scattering detectors) techniques. (c) 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020, 58, 824-830