Facile synthesis of AB(2)-type miktoarm star polymers through the combination of atom transfer radical polymerization and ring-opening polymerization

Erdogan T., Ozyurek Z., Hizal G., Tunca U.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.42, sa.10, ss.2313-2320, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 10
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/pola.20067
  • Dergi Adı: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2313-2320
  • Anahtar Kelimeler: atom transfer radical polymerization (ATRP), ring-opening polymerization (ROP), miktoarm star polymers, METHYL-METHACRYLATE, COPOLYMERS, INITIATOR, ACRYLATE, BLOCK
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

A novel miktofunctional initiator (1), 2-hydroxyethyl 3-[(2-bromopropanoyl)oxyl-2-{[(2-bromopropanoyl)oxylmethyll-2-methyl-propanoate, possessing one initiating site for ring-opening polymerization (ROP) and two initiating sites for atom transfer radical polymerization (ATRP), was synthesized in a three-step reaction sequence. This initiator was first used in the ROP of E-caprolactone, and this led to a corresponding polymer with secondary bromide end groups. The obtained poly(E-caprolactone) (PCL) was then used as a macroinitiator for the ATRP of tert-butyl acrylate methyl methaerylate, and this resulted in AB(2)-type PCL-[poly(tert-butyl acrylate)](2) or PCL-[poly(methyl methacrylate)], miktoarm star polymers with controlled molecular weights and low polydispersities (weight-average molecular weight/number-average molecular weight < 1.23) via the ROP-ATRP sequence. (c) 2004 Wiley Periodicals, Inc.