Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

Kiskan B., AKAR A., KIZILCAN N., Ustamehmetoglu B.

JOURNAL OF APPLIED POLYMER SCIENCE, vol.96, no.5, pp.1830-1834, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 96 Issue: 5
  • Publication Date: 2005
  • Doi Number: 10.1002/appp.21069
  • Journal Name: JOURNAL OF APPLIED POLYMER SCIENCE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1830-1834
  • Istanbul Technical University Affiliated: Yes

Abstract

1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolylpropyl 4-methyl-1-benzenesulfonate, and 1-H-pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH4)(2)Ce(NO3)(6) and FeCl3. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, H-1-NMR, and four-point probe conductivity. (c) 2005 Wiley Periodicals, Inc.