Soluble and conductive copolymers from 1-(hydroxyalkyl) pyrroles

Kiskan B. , AKAR A., KIZILCAN N. , Ustamehmetoglu B.

JOURNAL OF APPLIED POLYMER SCIENCE, vol.96, no.5, pp.1830-1834, 2005 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 96 Issue: 5
  • Publication Date: 2005
  • Doi Number: 10.1002/appp.21069
  • Title of Journal : JOURNAL OF APPLIED POLYMER SCIENCE
  • Page Numbers: pp.1830-1834

Abstract

1-Substituted pyrroles such as 1-(hydroxymethyl)pyrrole, 1-(3-hydroxypropyl) pyrrole, 1-H-1-pyrrolylmethyl 4-methyl-1-benzenesulfonate, 1-H-1-pyrrolylpropyl 4-methyl-1-benzenesulfonate, and 1-H-pyrrolylmethyloctanoate were synthesized and oxidative polymerized and copolymerized with pyrrole by using (NH4)(2)Ce(NO3)(6) and FeCl3. Some of the copolymers were slightly soluble in DMF and DMSO. The products were characterized by FTIR, H-1-NMR, and four-point probe conductivity. (c) 2005 Wiley Periodicals, Inc.