Synthesis of Block Copolymers by Combination of Atom Transfer Radical Polymerization and Visible Light-Induced Free Radical Promoted Cationic Polymerization

Kahveci M. Ü. , ACIK G., Yagci Y.

MACROMOLECULAR RAPID COMMUNICATIONS, cilt.33, sa.4, ss.309-313, 2012 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 33 Konu: 4
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1002/marc.201100641
  • Sayfa Sayıları: ss.309-313


A new synthetic approach for the preparation of block copolymers by mechanistic transformation from atom transfer radical polymerization (ATRP) to visible light-induced free radical promoted cationic polymerization is described. A series of halide end-functionalized polystyrenes with different molecular weights synthesized by ATRP were utilized as macro-coinitiators in dimanganese decacarbonyl [Mn2(CO)10] mediated free radical promoted cationic photopolymerization of cyclohexene oxide or isobutyl vinyl ether. Precursor polymers and corresponding block copolymers were characterized by spectral, chromatographic, and thermal analyses.