Eu(fod)(3) binding on the H-1-NMR spectra of bis (2 '-ethylbenzoate)ethylene glycol podands

Ünlü C. H., Yapar G., ERK C.

MAGNETIC RESONANCE IN CHEMISTRY, cilt.51, sa.1, ss.42-45, 2013 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 51 Sayı: 1
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1002/mrc.3904
  • Dergi Adı: MAGNETIC RESONANCE IN CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.42-45
  • Anahtar Kelimeler: carbonyl compounds, lanthanoids, magnetic dipolar shifts, ion binding, LANTHANIDE-INDUCED SHIFTS, CROWN-ETHERS, FLUORESCENCE SPECTROSCOPY, REAGENTS, RECOGNITION, ASSOCIATION, COMPLEXES, CONSTANTS
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

The complexing and selective binding constants of Eu(fod)(3) with bis(2'-ethylbenzoate) ethylene glycol podands having one to four oxyethylene groups was observed on their H-1-NMR spectra at 250 MHz and 295 K in CDCl3. The Eu(fod)(3) interaction displayed the selective binding role of oxygen on H2C-O-CH2 backbones with referring the H-1 chemical shifts.