Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Yıldız, Zehra; Önen, Hacer; Güngör, Atilla; Wang, Youjiang; Jacob, Karl

doi:10.1080/03602559.2017.1364382

Effects of NCO/OH Ratio and Reactive Diluent Type on the Adhesion Strength of Polyurethane Methacrylates for Cord/Rubber Composites

Atıf İçin Kopyala

Yıldız Z., Önen H. A., Güngör A., Wang Y., Jacob K.

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, cilt.57, sa.10, ss.935-944, 2018 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 57 Sayı: 10
Basım Tarihi: 2018
Doi Numarası: 10.1080/03602559.2017.1364382
Dergi Adı: POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.935-944
İstanbul Teknik Üniversitesi Adresli: Evet

Özet

A series of dual curable polyurethane methacrylate-based oligomers were synthesized by changing the NCO:OH ratio and then were included in adhesive formulations using trimethylolpropane trimethacrylate and tricyclodecane dimethanol diacrylate (TCDDA) as reactive diluents. The effects of NCO:OH ratio and reactive diluent type on the structural properties of UV-cured free films and adhesion properties between polyester cord/rubber surfaces were studied. The highest adhesion strength of the 103Ncm(-1) was obtained when the NCO:OH ratio was set as 4 and the TCDDA was used as a reactive diluent.