Toughness improvement and anisotropy in semicrystalline physical hydrogels

BILICI C., Karaarslan D., İDE S., Okay O.

POLYMER, vol.151, pp.208-217, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 151
  • Publication Date: 2018
  • Doi Number: 10.1016/j.polymer.2018.07.077
  • Journal Name: POLYMER
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.208-217
  • Istanbul Technical University Affiliated: Yes


A major challenge in the gel science is to create mechanically strong hydrogels with anisotropic properties as observed in many biological tissues. Here, we report a simple one-step method of producing high-strength physical hydrogels exhibiting microstructural and mechanical anisotropy. As the precursor material, we use semicrystalline shape-memory hydrogels consisting of poly(N, N-dimethylacrylamide) chains interconnected by n-octadecyl acrylate (C18A) segments forming crystalline domains and hydrophobic associations acting as switching segments and netpoints, respectively. To generate anisotropic microstructure, we impose a prestretching on the isotropic hydrogel sample above the melting temperature T-m of its crystalline domains followed by cooling below T-m under strain to fix the elongated shape of the gel sample. A significant microstructural and mechanical anisotropy was achieved that could be tuned by the magnitude of the prestretch ratio lambda(o). Directional brittle-to-ductile and ductile-to-brittle transitions could be induced by adjusting the prestretch ratio lambda(o). Smalland wide-angle X-ray scattering measurements and mechanical tests highlight a critical prestretch ratio lambda(o) at which the hydrogel exhibits the highest microstructural and mechanical anisotropy due to the finite extensibility of the network chains. At lambda(o) = 1.8, the hydrogel exhibits Young's moduli of 161 +/- 14 and 76 +/- 7 MPa, and toughness of 16 +/- 1 and 1.3 +/- 0.1 MJ M-3 along and perpendicular to the prestretching direction, respectively.