HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES


DABAK S., Gül A., BEKAROGLU O.

CHEMISCHE BERICHTE-RECUEIL, vol.127, no.10, pp.2009-2012, 1994 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 127 Issue: 10
  • Publication Date: 1994
  • Doi Number: 10.1002/cber.19941271025
  • Journal Name: CHEMISCHE BERICHTE-RECUEIL
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.2009-2012
  • Istanbul Technical University Affiliated: No

Abstract

Cyclotrimerization of 4,5-bis(hexylthio)phthalodinitrile (1) in 1-chloronaphthalene in the presence of BCl3 leads to the subphthalocyanine 4. Unsymmetrical phthalocyanines (5, 6) with six alkylthio substituents on three of the benzenoid units are synthesized by the reaction of 4 with an diminoisoindoline derivative (R' = H or NO2). These extremely soluble compounds are characterized by IR, H-1- and C-13-NMR as well as UV/Vis spectra.