HEXAKIS(ALKYLTHIO)-SUBSTITUTED UNSYMMETRICAL PHTHALOCYANINES


DABAK S., Gül A., BEKAROGLU O.

CHEMISCHE BERICHTE-RECUEIL, cilt.127, sa.10, ss.2009-2012, 1994 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 127 Sayı: 10
  • Basım Tarihi: 1994
  • Doi Numarası: 10.1002/cber.19941271025
  • Dergi Adı: CHEMISCHE BERICHTE-RECUEIL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2009-2012
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

Cyclotrimerization of 4,5-bis(hexylthio)phthalodinitrile (1) in 1-chloronaphthalene in the presence of BCl3 leads to the subphthalocyanine 4. Unsymmetrical phthalocyanines (5, 6) with six alkylthio substituents on three of the benzenoid units are synthesized by the reaction of 4 with an diminoisoindoline derivative (R' = H or NO2). These extremely soluble compounds are characterized by IR, H-1- and C-13-NMR as well as UV/Vis spectra.