Block copolymers of thiophene-capped poly(methyl methacrylate) with pyrrole


Alkan S. , TOPPARE L., HEPUZER Y., YAGCI Y.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, cilt.37, ss.4218-4225, 1999 (SCI İndekslerine Giren Dergi) identifier identifier

Özet

Poly(methyl methacrylate) with a thiophene end group having narrow polydispersity was prepared by the Atom Transfer Radical Polymerization (ATRP) technique. Subsequently, electrically conducting block copolymers of thiophene-capped poly(methyl methacrylate) with pyrrole were synthesized by using p-toluene sulfonic acid and sodium dodecyl sulfate as the supporting electrolytes via constant potential electrolysis. Characterization of the block copolymers were performed by CV, FTIR, SEM, TGA, and DSC analyses. Electrical conductivities were evaluated by the four-probe technique. (C) 1999 John Wiley & Sons, Inc.