Reactions of α,β-Enones with Diazo Compounds: Part 4: Reaction Pathways from (Z)- and (E)-α,β-Enones with Dimethyl Diazomalonate

Anac O., Güngör F. Ş., Kahveci Ç., Cansever M. Ş.

Helvetica Chimica Acta, vol.87, no.2, pp.408-415, 2004 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 87 Issue: 2
  • Publication Date: 2004
  • Doi Number: 10.1002/hlca.200490039
  • Journal Name: Helvetica Chimica Acta
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.408-415
  • Istanbul Technical University Affiliated: Yes

Abstract

In this study, (E)- and (Z)-enones carrying only a phenyl substituent at their C(β) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran derivatives, significant heterocycles in natural products.