Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors

de Carcer Garcia I. A., MERT SEVIM A., DE LA ESCOSURA A., TORRES T.

ORGANIC & BIOMOLECULAR CHEMISTRY, cilt.11, sa.14, ss.2237-2240, 2013 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 11 Sayı: 14
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1039/c3ob27468c
  • Dergi Adı: ORGANIC & BIOMOLECULAR CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2237-2240
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.