Synthesis of unsymmetrical carboxyphthalocyanines by palladium-catalyzed hydroxycarbonylation of iodo-substituted precursors


de Carcer Garcia I. A. , MERT SEVIM A., DE LA ESCOSURA A., TORRES T.

ORGANIC & BIOMOLECULAR CHEMISTRY, cilt.11, ss.2237-2240, 2013 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 11 Konu: 14
  • Basım Tarihi: 2013
  • Doi Numarası: 10.1039/c3ob27468c
  • Dergi Adı: ORGANIC & BIOMOLECULAR CHEMISTRY
  • Sayfa Sayıları: ss.2237-2240

Özet

Phthalocyanines (Pcs) containing a carboxylic acid functionality directly bound to the macrocycle have been synthesized, in one step and in good yields, from iodo-substituted Pc precursors. This methodology represents a convenient alternative to the commonly used method based on two consecutive oxidations of hydroxymethyl Pcs.