The synthesis, characterization, and electrochemistry of molecular cobaloxime/organocobaloxime: catalysts for cycloaddition of carbon dioxide and epoxides

Kilic A., Ulusoy M., Durgun M., Aytar E., Keles A., DAGDEVREN M., ...More

JOURNAL OF COORDINATION CHEMISTRY, vol.67, no.16, pp.2661-2679, 2014 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 67 Issue: 16
  • Publication Date: 2014
  • Doi Number: 10.1080/00958972.2014.948431
  • Title of Journal : JOURNAL OF COORDINATION CHEMISTRY
  • Page Numbers: pp.2661-2679
  • Keywords: Cobaloxime, Organocobaloxime, Electrochemistry, Spectroscopy, Carbon dioxide, SCHIFF-BASE LIGAND, CYCLIC CARBONATES, METAL-COMPLEXES, SPECTROSCOPIC CHARACTERIZATION, SALEN COMPLEXES, CO2, RU(II), TRANSFORMATION, COBALOXIME, NI(II)

Abstract

In this paper, the new cobaloxime (1), organocobaloxime (2) and multinuclear cobaloximes (3-10) were synthesized and characterized. These compounds were used as homogeneous catalysts for cyclic carbonate synthesis from carbon dioxide (CO2) and epoxides.