Orthogonal Multiple Click Reactions in Synthetic Polymer Chemistry


Tunca U.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, vol.52, no.22, pp.3147-3165, 2014 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Review
  • Volume: 52 Issue: 22
  • Publication Date: 2014
  • Doi Number: 10.1002/pola.27379
  • Title of Journal : JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
  • Page Numbers: pp.3147-3165
  • Keywords: copper catalyzed azide-alkyne cycloaddition (CuAAC), Diels-Alder, living polymerization, Michael thiol-ene, nitroxide radical coupling (NRC), nucleophilic substitution, orthogonal multifunctionalization, polymer-polymer conjugation, post-functionalization of polymer, strain promoted azide-alkyne cycloaddition (SPAAC), thiol-ene, thiol-yne, THIOL-ENE CLICK, ONE-POT SYNTHESIS, 3-MIKTOARM STAR TERPOLYMERS, SEQUENTIAL MICHAEL ADDITION, AZIDE-ALKYNE CYCLOADDITION, DIELS-ALDER REACTION, BLOCK-COPOLYMERS, POST-FUNCTIONALIZATION, HETEROGRAFT COPOLYMERS, TRIBLOCK COPOLYMERS

Abstract

This review highlights the concept of multiple click reaction strategy which is utilized for design and synthesis of well-defined complex macromolecular structures as well as multifunctionalization of well-defined polymers. This review examines the click combinations mainly from double to quadruple and additionally from the most frequently used to the least. The present review may also be regarded as an update for recent reviews dealing with specifically double and triple click reaction combinations in synthetic polymer chemistry. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 3147-3165