Spectroscopic and theoretical investigation of capillary-induced keto-enol tautomerism of phenacyl benzoylpyridinium-type photoinitiators


Yonet N., BICAK N., Yurtsever M. , YAGCI Y.

POLYMER INTERNATIONAL, cilt.56, ss.525-531, 2007 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 56 Konu: 4
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1002/pi.2161
  • Dergi Adı: POLYMER INTERNATIONAL
  • Sayfa Sayıları: ss.525-531

Özet

Phenacyl benzoylpyridinium (PBP) salts are effective photoinitiatiors for cationic polymerization. In this study, it is shown that PBP salts are stable in their keto forms, and undergo a reversible keto-enol tautomerization reaction when a capillary action is applied. Spectroscopic and theoretical methods are used to explain the existence of the enol forms in the capillary tube. (C) 2006 Society of Chemical Industry.