Synthesis, photophysical and photochemical properties of metal-free and zinc(II) phthalocyanines bearing alpha-naphtholbenzein units


Ozcesmeci M.

JOURNAL OF ORGANOMETALLIC CHEMISTRY, cilt.767, ss.16-21, 2014 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 767
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1016/j.jorganchem.2014.05.015
  • Dergi Adı: JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • Sayfa Sayıları: ss.16-21

Özet

Synthesis of metal-free and zinc (II) phthalocyanine complexes bearing alpha-naphtholbenzein units was described. Precursor required for the preparation of phthalocyanine complexes was prepared by nucleophilic aromatic substitution reaction between 4-nitrophthalonitrile and alpha-naphtholbenzein. Cyclotetramerization reactions of the new dinitrile derivative were accomplished in dry dimethylformamide at refluxed temperature. The new compounds were characterized by using elemental analyses, proton and carbon nuclear magnetic resonance, fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, fluorescence spectroscopy and mass spectrometry. The photophysical and photochemical properties of metal-free and zinc (II) phthalocyanines were studied in tetrahydrofuran. The fluorescence of the phthalocyanine complexes was effectively quenched by 1,4-benzoquinone (BQ) in tetrahydrofuran. The effect of the concentration on the aggregation properties and solvent effects on the absorption spectra of phthalocyanine complexes were also investigated. (C) 2014 Elsevier B. V. All rights reserved.