A new azo initiator for the synthesis of polymers with pyrene terminal groups


Hepuzer Y. , GUVENER U., YAGCI Y.

POLYMER BULLETIN, cilt.52, ss.17-23, 2004 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 52 Konu: 1
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1007/s00289-004-0244-6
  • Dergi Adı: POLYMER BULLETIN
  • Sayfa Sayıları: ss.17-23

Özet

4,4'-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4'-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporation of terminal groups were confirmed by spectral measurements.