A new azo initiator for the synthesis of polymers with pyrene terminal groups

Hepuzer Y., GUVENER U., YAGCI Y.

POLYMER BULLETIN, cilt.52, sa.1, ss.17-23, 2004 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 52 Sayı: 1
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1007/s00289-004-0244-6
  • Dergi Adı: POLYMER BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.17-23
  • İstanbul Teknik Üniversitesi Adresli: Hayır

Özet

4,4'-azobis(4-cyanopyrenylmethyl pentanoate) (ACPMP) was synthesized by the reaction of pyrenylmethanol with 4,4'-azobis(4-cyanopentanoyl chloride) (ACPC). ACPMP was further used in the synthesis of polystyrene with pyrene terminal groups by using conventional free radical polymerization (FRP) and stable free radical polymerization (SFRP) techniques. Incorporation of terminal groups were confirmed by spectral measurements.