Visible-Light-Induced Copper(I)-Catalyzed Azide-Alkyne Cycloaddition Initiated by Zinc Oxide Semiconductor Nanoparticles

Yetiskin O., DADASHI-SILAB S., KHAN S. B., ASIRI A. M., Yagci Y.

ASIAN JOURNAL OF ORGANIC CHEMISTRY, cilt.4, sa.5, ss.442-444, 2015 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 4 Sayı: 5
  • Basım Tarihi: 2015
  • Doi Numarası: 10.1002/ajoc.201500077
  • Dergi Adı: ASIAN JOURNAL OF ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.442-444
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

A visible-light-induced protocol for copper(I)-catalyzed azide-alkyne cycloaddition is reported. With the aid of semiconductor zinc oxide nanoparticles (ZnO NPs) as a heterogeneous photocatalyst, a copper(I) catalyst is formed. A variety of azide and alkyne components have been examined and the system tolerates different substrates in the click reaction well.