Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst


Kilic A., Palali A. A. , Durgun M., Tasci Z., Ulusoy M., DAGDEVREN M., ...More

INORGANICA CHIMICA ACTA, vol.394, pp.635-644, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 394
  • Publication Date: 2013
  • Doi Number: 10.1016/j.ica.2012.09.020
  • Journal Name: INORGANICA CHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.635-644
  • Keywords: Oxime complexes, Mass spectra, Electrochemistry, Carbon dioxide, Cyclic carbonate, TRANSITION-METAL-COMPLEXES, REDOX PROPERTIES, ALTERNATING COPOLYMERIZATION, SPECTRAL CHARACTERIZATION, SCHIFF-BASE, CU-II, NI-II, PROPYLENE-OXIDE, SALEN COMPLEXES, STYRENE OXIDE
  • Istanbul Technical University Affiliated: Yes

Abstract

Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by H-1 and C-13 NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)(2)] complex (2). Then, the intramolecular O-H center dot center dot center dot O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)(2)Cu-2(N-N)(2)](ClO4)(2) oxime complexes (3-7) where N-N = 2,2'-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3'-dicarboxy-2,2'-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime)(2)] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes. (C) 2012 Elsevier B. V. All rights reserved.