Synthesis and characterization of new soluble metallophthalocyanines with bulky substituents


Gumus G. , Gül A. , Ahsen V.

NEW JOURNAL OF CHEMISTRY, cilt.21, sa.5, ss.589-594, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 21 Konu: 5
  • Basım Tarihi: 1997
  • Dergi Adı: NEW JOURNAL OF CHEMISTRY
  • Sayfa Sayıları: ss.589-594

Özet

Metallophthalocyanines 4-7 [M=Cu(ll), Ni(ll), Zn(ll) or Co(ll)] carrying eight decyltosylaminomethyl groups in peripheral positions have been synthesized from 1,2-dibromo-(3a) or 1,2-dicyano-4,5-bis(decyltosylaminomethyl)benzene (3b) in the presence of the corresponding anhydrous metal salt, These soluble phthalocyanines have been characterized by elemental analysis, IR, H-1 and C-13 NMR, UV-visible, and mass spectra, the spectral data indicates the presence of essentially unaggregated species.