BIFUNCTIONAL INITIATORS .5. PREPARATION OF POLYMERS WITH AZO LINKAGE BY USING AZO-BENZOIN INITIATORS AND THEIR USE IN BLOCK COPOLYMERIZATION

HEPUZER, Y; BEKTAS, M; DENIZLIGIL, S; ONEN, A; YAGCI, Yusuf

BIFUNCTIONAL INITIATORS .5. PREPARATION OF POLYMERS WITH AZO LINKAGE BY USING AZO-BENZOIN INITIATORS AND THEIR USE IN BLOCK COPOLYMERIZATION

Atıf İçin Kopyala

HEPUZER Y., BEKTAS M., DENIZLIGIL S., ONEN A., YAGCI Y.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, ss.111-115, 1993 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1993
Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.111-115
İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Polymers with labile azo groups in the main chain were prepared by free radical polymerization initiated by photodecomposition of 4,4'-azo-bis(4-cyanopentanoyl)-bis benzoin (ACPB) in methylene chloride solution at lambda=350 nm. These polymers were used as initiator for free radical polymerization of a second monomer to yield block copolymers. Free radical sites located at the chain ends were generated by the thermolysis of the azo groups present in the polymer.