Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s

YILDIRIM A., Kiskan B., DEMIREL A. L., Yagci Y.

EUROPEAN POLYMER JOURNAL, cilt.42, sa.11, ss.3006-3014, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 11
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1016/j.eurpolymj.2006.07.019
  • Dergi Adı: EUROPEAN POLYMER JOURNAL
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3006-3014
  • İstanbul Teknik Üniversitesi Adresli: Evet

Özet

Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and H-1-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM). (c) 2006 Published by Elsevier Ltd.