Synthesis, characterization and properties of naphthoxazine-functional poly(propyleneoxide)s


YILDIRIM A., Kiskan B. , DEMIREL A. L. , Yagci Y.

EUROPEAN POLYMER JOURNAL, vol.42, no.11, pp.3006-3014, 2006 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 11
  • Publication Date: 2006
  • Doi Number: 10.1016/j.eurpolymj.2006.07.019
  • Title of Journal : EUROPEAN POLYMER JOURNAL
  • Page Numbers: pp.3006-3014

Abstract

Thermally curable naphthoxazine-functionalized polymers were synthesized by the reaction of linear (diamines) and branched (triamines) poly(propyleneoxide)s (Jeffamine series) having various molecular weights, with p-formaldehyde, and 2-naphthol. The structures of the resulting polymers were characterized by using FT-IR and H-1-NMR. In addition, curing behavior of these polymers was studied using differential scanning calorimeter (DSC). Hydrophilicity of these polymers, both in cured and non-cured states, was investigated by water contact angle measurements. The surface topographies of the polymers were also examined by atomic force microscope (AFM). (c) 2006 Published by Elsevier Ltd.